积分形式非局部本构关系的界带分析方法

基于Hamilton体系研究了Eringen的非局部线弹性本构关系.Eringen的非局部线弹性理论存在积分型和微分型两类本构关系.由于方程的形式简单,目前多采用微分型本构;而积分型本构方程是典型的积分-微分方程,数值求解较为困难.在分析结构力学中提出的界带分析方法,成功求解了时间滞后问题的积分-微分方程.根据分析动力学与分析结构力学的模拟关系,将界带分析方法引入到非局部理论的积分型本构方程,可以实现积分-微分方程的数值求解.通过杆件的振动分析算例验证了该套理论算法的准确性和可行性,也指出了辛体系算法在非局部力学问题中的潜力.     

Exact solution for warping of spatial curved beams in natural coordinates

The purpose of the paper is to present an exact analytical solution of a spatial curved beam under multiple loads based on the existing theory. The transverse shear deformation and torsion-related warping effects are taken into account. By using this solution, a plane curved beam subjected to uniform vertical loads and torsions is analyzed. Accuracy and efficiency of present theory are demonstrated by comparing its numerical results with Heins＇ solution. Furthermore, the effects of the transverse shear deformation and torsion-related warping on deformation of the beam are discussed.     

等离子体制取羟自由基降解苯酚溶液及其历程的UV研究

研究了利用强电离放电产生等离子体方法制取羟基自由基氧化降解高浓度苯酚废水。当羟基自由基浓度达到1 037 mg·L-1时,初始浓度为1 215 mg·L-1的废水降解率达99.11%;初始浓度为8 853 mg·L-1的废水苯酚浓度下降到6 250 mg·L-1,1 mg羟基自由基可处理苯酚2.5 mg。在同样羟自由基浓度下,苯酚初始浓度越小,去除率越高;但初始浓度越高,处理的绝对量越大。阐述并解释了不同降解阶段废水pH值、电导率与羟基自由基浓度变化的关系。随着羟自由基浓度的增大,废水酸碱性由接近中性逐渐转为酸性,浓度越大,酸性越强;继续增大羟自由基浓度,变化渐趋平缓。随着羟自由基的通入,电导率有一个微小的降低阶段然后开始上升,说明苯酚不断的被氧化为有机酸。通过紫外图谱和色谱分析了降解中间产物,表明氧化初始阶段邻苯二酚、对苯二酚和苯醌是其中重要的化合物。     

新型紫外光固化粘接性单体的合成与应用研究

以甲基丙烯酸、1,10-癸二醇和三氯硫磷为主要原料合成出了紫外光固化粘接性单体10-甲基丙烯酰氧癸基硫磷酸二氯.用¹H-NMR、³¹P-NMR和FT-IR对产物结构进行了表征确认.通过剪切强度的测试评价了其对复合树脂与钛合金、钴铬合金之间的粘接所起到的作用.结果表明,10-甲基丙烯酰氧癸基硫磷酸二氯与水和三乙胺的混合溶液能够促进复合树脂与钛合金、钴铬合金的粘接,剪切强度分别达到17.3 MPa、18.1 MPa.     

Single-parameter-learning-based robust adaptive control of dynamic positioning ships considering thruster system dynamics in the input saturation state

Nonlinear Dynamics - The focus of this paper is presented on robust adaptive dynamic positioning control in the face of thruster system dynamics. In the maritime domain, it considers the issues of...     

一种基于HLLC算法的Mie-Grüneisen多介质混合模型

建立一种修正的HLLC （Harten-Lax-Van Leer-Contact）格式下稳定的Mie-Grüneisen多介质混合计算模型.Mie-Grüneisen混合模型中的通量包括守恒和非守恒两个部分，原始的HLLC格式对守恒部分适用，但是原始的HLLC格式直接用于非守恒部分，很难控制住数值振荡的产生.在原始格式中，间断面的移动速度为间断网格的左侧或右侧速度，修正后替换为网格中的平均速度，经过修正后，对HLLC格式重新进行推导，并随之扩展到二维问题.数值实验表明，利用修改后的HLLC格式，Mie-Grüneisen混合模型可以取得较好的稳定性和准确性.     

Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones

A new class of hemilabile unsymmetrical 2-(1-arylimino)-6-(pyzazol-1-yl)pyridine ligands and their ruthenium(II) and nickel(II) NNN complexes were synthesized. The Ru(II) complex catalysts have been fully characterized and exhibited good to excellent catalytic activity in the transfer hydrogenation (TH) of ketones in refluxing 2-propanol. These results have demonstrated rare examples of active ruthenium(II) NNN complex catalysts that do not feature a N-H functionality for TH of ketones.     

Photoluminescence characteristics of Pr3+ in ThO2: interplay of defects in a photo-induced charge transfer

Photo-luminescence studies of Pr³⁺ activated thorium oxide phosphor have revealed that mainly ³P→³H₄ and ¹D₂→³H₄ transitions with life-time of 30 and 600 μs are observed in this sample. An exponential reduction in the emission intensity of Pr³⁺ ions was observed on following continuous excitation with 275 nm corresponding to the f–d transition band of Pr³⁺ ions. Such a reduction in emission intensity was observed at all temperatures investigated in the range 90–330 K. The emission intensity recovered partially on dark storage only above 180 K. The recovery of emission intensity was also observed on the illumination of pre-exposed sample to light in the wavelength region 300–430 nm. Following illumination with 275 nm, Pr³⁺ activated thorium oxide phosphor has displayed a weak thermally stimulated luminescence. These results thus suggest that the optical excitation dynamically changes the state of the system under observation, and that changes are occurring in the valence state of Pr ions due to e/h transfer process on 275-nm exposure. On dark storage and also on 365-nm illumination of the pre-exposed sample, e/h traps recombine to cause emission signal recovery. The analysis of data on reduction in intensity obtained with exposure to 275 nm suggests the likelihood of the of Pr³⁺ ions existing at three different sites. The activation energies associated with the release of electrons from excited Pr³⁺ ions at different sites were determined from the temperature dependence of the photo-induced charge transfer process.     

基于尾流时程目标识别的流场参数选择研究

浸入流场中的固体壁面会形成高度复杂且具有一定特征的尾流流场, 利用尾流所包含的信息对物体的外形特征进行识别具有重要的应用价值. 然而, 在较高雷诺数情况下尾流流场形态及其时序特征复杂, 难以通过传统的数学物理方法对流场信号进行特征的识别与提取. 本文提出了基于尾流时程数据深度学习的流场特征提取与分析方法, 实现了基于一点的物理量时程进行流场中物体外形的识别; 同时, 对流场中不同物理参数时程的识别精度与识别结果进行分析与研究, 得到适用于目标识别的最优物理量参数. 通过对圆柱和方柱的尾流数据研究结果表明, 本文提出的基于卷积神经网络的模型具有好的训练收敛性和高的预测精度, 能够识别并提取得到时程数据中包含的流场特征, 采用流场横向速度时程作为物体外形识别信号的模型准确率高. 证明了本方法用于浸入流场中物体外形识别的可行性, 是一种目标识别的高精度方法.      

Global exponential stability of nonresident computer virus models

This paper is concerned with nonresident computer virus models which are defined on the nonnegative real vector space. By using differential inequality technique, we employ a novel argument to show that the virus-free equilibrium is globally exponentially stable, and the exponential convergent rate can be unveiled. Moreover, a numerical simulation is given to demonstrate our theoretical results.